EFFECT OF HVOF PROCESS PARAMETERS ON THE STRUCTURE AND MECHANICAL PERFORMANCE OF ZRCN COATINGS
Keywords:
ZrCN, HVOF, protective coatings, adhesion, microhardness, wear resistance, microstructureAbstract
The paper investigates the structural and mechanical properties of zirconium carbonitride (ZrCN) coatings deposited by high-velocity oxygen flame spraying (HVOF) on a U8G steel substrate. The effect of spraying process parameters on the adhesion strength and microhardness of the coatings is considered. It is established that changing the HVOF modes significantly affects the formation of the microstructure, density and quality of the coating–substrate interphase boundary. All the obtained coatings are shown to have high microhardness, exceeding that of the original material by more than 4–5 times. The maximum values of both adhesion strength and microhardness are achieved at optimal spraying parameters (mode c), which is associated with improved particle flattening, reduced porosity and the formation of a denser coating structure. The obtained results confirm the potential of using ZrCN coatings obtained by the HVOF method to increase the wear resistance and durability of parts operating under conditions of intense mechanical and thermal loads.
References
1. Yao S.H., Su Y.L., Kao W.H., Cheng K.W. Structural and tribological properties of ZrCN coatings // Materials Letters. – 2005. – Vol. 59. – P. 3230–3233. – DOI: https://doi.org/10.1016/j.matlet.2005.05.022.
2. Kudapa S., Narasimhan K., Boppana P., Russel W.C. Deposition and characterization of Zr-based coatings // Surface and Coatings Technology. – 1999. – Vol. 120–121. – P. 259–266. – DOI: https://doi.org/10.1016/S0257-8972(99)00432-9.
3. Grigore E., Ruset C., Li X., Dong H. Properties of ZrCN coatings // Surface and Coatings Technology. – 2010. – Vol. 204. – P. 1889–1893. – DOI: https://doi.org/10.1016/j.surfcoat.2009.11.029.
4. Balaceanu M., Petreus T., Braic V., Zoita C.N., Vladescu A., Cotrutz C.E., Braic M. Characterization of ZrCN coatings // Surface and Coatings Technology. – 2010. – Vol. 204. – P. 2046–2050. – DOI: https://doi.org/10.1016/j.surfcoat.2009.12.012.
5. Rie K.-T., Wöhle J. Zr-based hard coatings // Surface and Coatings Technology. – 1999. – Vol. 112. – P. 226–231. – DOI: https://doi.org/10.1016/S0257-8972(98)00740-6.
6. Gu J.-D., Chen P.-L. Characterization of zirconium carbonitride coatings // Surface and Coatings Technology. – 2006. – Vol. 200. – P. 3341–3345. – DOI: https://doi.org/10.1016/j.surfcoat.2005.01.070.
7. Larijani M.M., Zanjanbar M.B., Majdabadi A. Mechanical properties of ZrCN coatings // Journal of Alloys and Compounds. – 2010. – Vol. 492. – P. 735–739. – DOI: https://doi.org/10.1016/j.jallcom.2009.11.135.
8. Vepřek S., Nesládek P., Niederhofer A., Glatz F., Jílek M., Šíma M. Superhard nanocomposite coatings // Surface and Coatings Technology. – 1998. – Vol. 108–109. – P. 138–147. – DOI: https://doi.org/10.1016/S0257-8972(98)00666-8.
9. Musil J., Poláková H. Hard nanocomposite coatings // Surface and Coatings Technology. – 2000. – Vol. 99. – P. 127–131. – DOI: https://doi.org/10.1016/S0257-8972(99)00263-4.
10. Carvalho S., Ribeiro E., Rebouta L., Tavares C., Mendonça J.P., Caetano Monteiro A., Carvalho N.J.M., De Hosson J.Th.M., Cavaleiro A. Mechanical properties of ZrCN coatings // Surface and Coatings Technology. – 2004. – Vol. 177–178. – P. 459–468. – DOI: https://doi.org/10.1016/S0257-8972(03)00646-9.
11. Field S.K., Jarratt M., Teer D.G. Tribological behaviour of hard coatings // Tribology International. – 2004. – Vol. 37. – P. 949–956. – DOI: https://doi.org/10.1016/j.triboint.2004.05.001.
12. Zehnder T., Patscheider J. Structural properties of ZrCN coatings // Surface and Coatings Technology. – 2000. – Vol. 138. – P. 133–139. – DOI: https://doi.org/10.1016/S0257-8972(00)01034-3.
13. Soldán J., Neidhardt J., Sartory B., Kaindl R., Čerstvý R., Mayrhofer P.H., Tessadri R., Polcik P., Lechthaler M., Mitterer C. Multilayer hard coatings // Surface and Coatings Technology. – 2008. – Vol. 202. – P. 3555–3562. – DOI: https://doi.org/10.1016/j.surfcoat.2007.11.030.
14. Martínez-Martínez D., Sánchez-López J.C., Rojas T.C., Fernández A., Eaton P., Belin M. Microstructural analysis of coatings // Thin Solid Films. – 2005. – Vol. 472. – P. 64–71. – DOI: https://doi.org/10.1016/j.tsf.2004.05.084.
15. Karlsson L., Hultman L., Johansson M.P., Sundgren J.E., Ljungcrantz H. Growth of ZrCN coatings // Surface and Coatings Technology. – 2000. – Vol. 126. – P. 1–14. – DOI: https://doi.org/10.1016/S0257-8972(99)00689-4.
16. Bull S.J., Bhat D.G., Staia M.H. Nanostructured hard coatings // Surface and Coatings Technology. – 2003. – Vol. 163–164. – P. 499–506. – DOI: https://doi.org/10.1016/S0257-8972(02)00635-8.
17. Bull S.J., Bhat D.G., Staia M.H. Mechanical behaviour of hard coatings // Surface and Coatings Technology. – 2003. – Vol. 165. – P. 507–513. – DOI: https://doi.org/10.1016/S0257-8972(02)00766-2.
18. Polcar T., Novák R., Široký P. Tribological performance of coatings // Wear. – 2006. – Vol. 260. – P. 40–49. – DOI: https://doi.org/10.1016/j.wear.2005.01.007.
19. Rebelo de Figueiredo M., Neidhardt J., Kaindl R., Reiter A., Tessadri R., Mitterer C. Wear behaviour of hard coatings // Wear. – 2008. – Vol. 265. – P. 525–533. – DOI: https://doi.org/10.1016/j.wear.2007.12.010.
20. Balaceanu M., Braic M., Braic V., Pavelescu G. Properties of Zr-based coatings // Surface and Coatings Technology. – 2005. – Vol. 200. – P. 1084–1089. – DOI: https://doi.org/10.1016/j.surfcoat.2005.02.165.
21. Kuznetsova T.A., et al. Effect of atmosphere during deposition on the morphology, mechanical properties and microfriction of Zr-based coatings // Advanced Materials Modelling for Mechanical, Medical and Biological Applications. – Cham: Springer, 2021. – Vol. 155. – P. 271–319. – DOI: https://doi.org/10.1007/978-3-030-68622-4_12.
22. Huang S.H., et al. Microstructure and mechanical properties evaluation of cathodic arc deposited CrCN/ZrCN multilayer coatings // Journal of Alloys and Compounds. – 2005. – Vol. 803. – P. 1005–1015. – DOI: https://doi.org/10.1016/j.jallcom.2019.1005.
23. 23.Mueller R., et al. Nanoparticle synthesis and deposition: processing aspects // Powder Technology. – 2003. – Vol. 140. – P. 40–48.
24. 24.Mueller R., et al. Gas-phase synthesis of nanoparticles // Journal of Nanoparticle Research. – 2004. – Vol. 6. – P. 39–50.
25. Wegner K., Pratsinis S.E. Scale-up of nanoparticle synthesis in diffusion flame reactors // Chemical Engineering Science. – 2003. – Vol. 58. – P. 4581–4589.
26. Xun Y., et al. Processing of nanostructured coatings by HVOF spraying // Surface and Coatings Technology. – 2004. – Vol. 179. – P. 262–268.
27. He J., Schoenung J.M. Nanostructured coatings by thermal spraying // Materials Science and Engineering A. – 2000. – Vol. 336. – P. 274–319.
28. Ajdelsztajn L., et al. Processing and properties of nanostructured coatings // Surface and Coatings Technology. – 2002. – Vol. 151–152. – P. 1–7.
29. Ajdelsztajn L., et al. Processing and properties of nanostructured coatings // Surface and Coatings Technology. – 2002. – Vol. 151–152. – P. 1–7.Anusha K., Routara B.C., Guha S. A review on high-velocity oxy-fuel (HVOF) coating technique // Journal of the Institution of Engineers (India): Series D. – 2023. – Vol. 104. – P. 831–848. – DOI: https://doi.org/10.1007/s40033-022-00434-x.
30. Kurbanbekov S.R., et al. Effect of HVOF spraying parameters on the structural-phase composition and mechanical properties of ZrCN coating // Bulletin of the Karaganda University. Physics Series. – 2025. – No. 3. – P. 31–40.
31. Harrison R. Processing and characterisation of ZrCxNy ceramics as a function of stoichiometry via carbothermic reduction-nitridation: PhD thesis. – London: Imperial College London, 2015.
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